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Flammable materials should be labeled with clear and specific information to ensure safety and compliance with regulations. The correct choice states that they should be labeled with "FLAMMABLE 6." This labeling indicates the type of hazard present and helps immediate identification of the flammability risk associated with the material.

The number 6 may refer to a classification or code that further specifies the material's characteristics within established guidelines, depending on the context or regulatory framework it is used within. Proper labeling is critical for the identification and management of hazards, and it assists workers in understanding the risks involved in handling flammable substances.

Clear and specific labeling, like "FLAMMABLE 6," allows for training and response plans to be effectively developed around the identified risks, ensuring safety protocols are followed.

Other labeling options may lack clarity or specificity required for effective hazard communication. For instance, large red signs may signify danger but don’t communicate the specific risk associated with flammable materials. Labels stating "Hazardous" are too vague and could encompass a variety of dangerous substances without indicating flammability. Not labeling at all presents a significant risk, as it can lead to uninformed handling and potential accidents involving flammable materials.